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Pentose Wikipedia.A pentose is a monosaccharide with five carbonatoms.Pentoses are organized into two groups.Aldopentoses have an aldehydefunctional group at position 1.Ketopentoses have a ketone functional group in position 2 or 3.AldopentoseseditThe aldopentoses have three chiral centers and therefore eight different 23 stereoisomers are possible.KetopentoseseditThe 2 ketopentoses have two chiral centers, and therefore four different stereoisomers are possible 22.Citing Patent Filing date Publication date Applicant Title US2958579 Jun 20, 1955 Nov 1, 1960 Union Carbide Corp Process for manufacture of molecular sieve.INEOS Olefins Polymers key products include Ethylene, Propylene, Butadiene, Benzene and Polyolefins, all from four cracker and polymer sites.This review looks at the main processes available for the production of light olefins with a focus on maximizing the production of propylene.Maximization of. The 3 ketopentoses are rare.PropertieseditThe aldehyde and ketone functional groups in these carbohydrates react with neighbouring hydroxyl functional groups to form intramolecularhemiacetals and hemimetals, respectively.The resulting ring structure is related to furan, and is termed a furanose.The ring spontaneously opens and closes, allowing rotation to occur about the bond between the carbonyl group and the neighbouring carbon atom yielding two distinct configurations and. Virtual Tablet Interface 7 Crack Derby . This process is termed mutarotation.Ribose is a constituent of RNA, and the related deoxyribose of DNA.A polymer composed of pentose sugars is called a pentosan.Tollens test for pentoseseditThe Tollens test for pentoses relies on reaction of the furfural with phloroglucinol to produce a colored compound with high molar absorptivity.See alsoeditReferenceseditPentose, Merriam WebsterOshitna, K., and Tollens, B., Ueber Spectral reactionen des Methylfurfurols.Ber. Dtsch. Chem.Ges. 3. 4, 1. 42.Depositphotos_33583801_s.jpg' alt='Steam Cracking For Olefins Production Process' title='Steam Cracking For Olefins Production Process' />Reactivity of naphtha fractions for light olefins production.In order for propylene to be produced, the cracking of FCC naphtha has to be carried out at high temperatures, but increasing temperature favors thermal cracking which leads to the formation of dry gas from hydrocarbon 2.Raising the temperature is most effective in controlling the exothermic hydrogen transfer reaction and accelerating the catalytic cracking which is endothermic.In a commercial unit, the high reaction temperature is achieved by raising the catalyst circulation rate.This helps to improve the rate of reaction as well as the propylene yield.Since the hydrogen transfer reaction is a secondary reaction, it is better controlled using a short contact time to limit the hydrogenation of olefin over cracking reactions 3, 8.By increasing CO ratio, contact opportunities between catalyst active centers and hydrocarbon molecules are improved leading to enhanced selectivity and yields of light olefins such as propylene and butylene during catalytic cracking of hydrocarbons.As can be seen from Figs.CO, the conversion, total light olefin yield and the yields of dry gas increase.The reactions of olefins take place more easily at high CO due to its high reactivity over catalyst active centers and this explains the high yield of light olefins with LCN as feed.Compared to olefins, paraffins have a lower reactivity towards cracking due to energetically more difficult formation of carbenium ions.Increasing the catalyst to oil ratio increases the severity of the hydrogenation and cracking reaction leading to over cracking and more saturates.Subsequently, more dry gas is produced, which in this case is made up of mainly methane and ethane.For thermal cracking, free radicals are formed through hydrocarbons splitting their CC bonds and HC bonds, and then inclined to undergoing alpha scission, beta scission, and polymerization to produce H2, methane, ethylene and coke 2.However, at higher CO, thermal cracking is effectively inhibited as hydrocarbons have more opportunities to contact with active centres of catalysts leading to catalytic cracking.Therefore, the yields of C1 and H2 decrease as the CO is enhanced.But because of more small pore zeolite ZSM 5 being available at higher CO, which are more favorable for the formation of ethane, therefore, mostly the yields of ethylene and ethane in dry gas are enhanced.Also, a very high CO does not necessarily lead to a significant increase of propylene and butylene due to the enhanced hydrogen transfer reaction stemming from the presence of more Y zeolite based catalyst.As Y zeolite based catalyst are used in FCC units, the bimolecular mechanism competes with cracking to form light olefins.For maximizing light olefin production, FCC units should be operated at high severity, which includes high CO ratios, high temperatures, and short contact time to minimize the hydrogen transfer reaction.It has been well established that the conversion of light hydrocarbons occurs via carbenium ion chemistry 1.The steps for the catalytic cracking mechanism of alkanes 1.Fig. 8 Fig. 8. Illustration of cracking mechanism.A carbenium ion is first generated by protonation of a paraffin molecule on a Brnsted acid site to form a carbonium ion a pentacoordinated ion,2.The carbonium ion then immediately cracks to give a carbenium ion and a paraffin.Then, the carbenium ion cracks to give an olefin and an acidic proton on the surface of the catalyst.For the Bimolecular mechanism, the carbenium ion in step 3 acts as an active center by reacting with a feed paraffin molecule to form a larger molecule that further cracks according to the following steps 4.A paraffin reacts with carbenium ion to form a smaller paraffin and a bigger carbenium ion.The bigger carbenium ion then cracks into an olefin and a carbenium ion through beta scission.The bimolecular mechanism explain the hydrogen transfer reaction and the formation of heavier compounds than those found in the feed such as coke, light cycle oil and heavy cycle oil.Hydrogen transfer reaction usually occurs from an olefin to a carbenium ion on the catalyst surface giving rise to a paraffin and a hydrogen deficient species allylcarbenium ion 2.The hydrogen deficient species can be further transformed into aromatics and coke via further dehydrogenation and cyclization reactions.Hydrogen transfer reactions are prevalent at high conversions and help to decrease the selectivity to olefins as shown in Fig.Thus, a bimolecular cracking mechanism will preferentially lead to the formation of aromatics from the naphthenes, since the carbenium may be directly formed from the feed molecule through a hydride transfer, while a monomolecular cracking mechanism will preferentially lead to short olefins.Then, the balance between hydrogen transfer reactions and cracking reactions will be critical in orienting the selectivity of olefins and naphthenes conversion towards either propylene or gasoline range aromatics or paraffins.The balance between these two mechanisms will depend on the surface coverage by carbenium ions.The presence of carbenium ions is influenced by reaction temperature and catalyst acid site density.The higher number of acid sites favors the bimolecular mechanism.The acid site density may be decreased by dealumination or coking.Catalysts with small pore sizes such as ZSM 5 favor the monomolecular mechanism since there is limited space for the formation of the intermediate species for the bimolecular mechanism.Propylene production is hampered by hydrogen transfer reaction as it consumes the olefins generated by the catalytic cracking.This hydrogen transfer is generally known to have a bimolecular reaction and it depends on the acidity of the catalyst, contact time and reaction temperature. |
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